Use the following steps to grant an existing database user db_owner permissions
Theses steps assume that you are connected to SQL Database in Object Explorer in SSMS and are connected to your SQL Database logical server as a server-level principal administrator or with a user account with permissions to grant user permissions.
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In Object Explorer, expand the Databases node and select the database with the user to which you wish to grant dbo permissions.
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Right-click the selected database and then click Query.
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In the query window, edit and use the following Transact-SQL statement to grant dbo permissions to a specified user.